Cocamidopropyl betaineby Naturallythinking Safety Data Sheet (SDS)

SDS for Cocamidopropyl betaine

Safety Data Sheet (SDS) dated 20/09/2019

Batch Number: FRAMECPSR


Section 1: Identification of Product and Supplier

Product Name: Cocamidopropyl betaine
Product Number: 5060330630570
Brand: Naturallythinking
Supplier: Naturallythinking, The Tramsheds, Coomber Way, Croydon, Surrey, CR0 4TQ
Contact Telephone: 020 8689 6489
Contact Email: support@naturallythinking.eu

Section 2: Hazards IDENTIFICATION

2.1. Classification of the substance or mixture

EC regulation criteria 1272/2008 (CLP):

Danger, Eye Dam. 1, Causes serious eye damage. 
Aquatic Chronic 3, Harmful to aquatic life with long lasting effects. 

Adverse physicochemical, human health and environmental effects:

No other hazards

2.2. Label elements Hazard pictograms:

Danger

Hazard statements:

H318 Causes Serious eye damage.
H412 Harmful to aquatic life with long last effects.

Precautionary Statements

P273 Avoid release to the environment
P280 Wear protective gloves / protective clothing / eye protection / face protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
310 Immediately call a POISON CENTER/doctor/...
P501 Dispose of contents/container in accordance with applicable regulations

Special Provisions:

None

Contains

Cocamidopropyl betaine

Special provisions according to Annex XVII of REACH and subsequent amendments:

None

2.3. Other hazards vPvB Substances: None - PBT Substances: None

Other Hazards:

No other hazards 

Section 3: Composition and information on Ingredients

Inci: Cocamidopropyl betaine
Cas: 61789-40-0
Einecs: 263-058-8

3.1. Substances

N.A.

3.2. Mixtures

Product type and use: Sufactants 
Hazardous components within the meaning of the CLP regulation and related classification:

Qty Name Ident. Number Classification
>= 30% - < 40% Cocamidopropyl betaine CAS: 147170-443
EC: 931333-8
REACH: 01-2119489410-39-XXX
3.3/1 Eye Dam.1 H318
4.1/C3 Aquatic Chronic 3 H412
>= 1% - < 3% Coconut fatty acids CAS: 61788-47-4
EC: 262-978-7
 
3.3/2 Eye Irrit. 2 H319
3.2/2 Skin Irrit. 2 H315
>= 0.25% - < 0.5% Cocco, N-[3- (dimetilamino)propil] ammide  CAS: 68140-01-2
EC: 268-771-8
3.1/4 Oral Acute Tox. 4H320
4.1/A1 Aquatic Acute 1 H400

 

Section 4: First aid measures

4.1. Description of first aid measures

In case of skin contact:

Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. OBTAIN IMMEDIATE MEDICAL ATTENTION. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose off safely.

In case of eyes contact:

After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately. Protect uninjured eye.

In case of Ingestion:

Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.

In case of Inhalation:

Remove casualty to fresh air and keep warm and at rest.

4.2. Most important symptoms and effects, both acute and delayed

None

4.3. Indication of any immediate medical attention and special treatment needed

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: None 

Section 5: Fire - Fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons: None in particular.

5.2. Special hazards arising from the substance or mixture

Do not inhale explosion and combustion gases. Burning produces heavy smoke.

5.3. Advice for firefighters Use suitable breathing apparatus.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8.

6.2. Environmental precautions

Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand

6.3. Methods and material for containment and cleaning up Wash with plenty of water.

6.4. Reference to other sections See also section 8 and 13

Section 7: Handling and Storage

7.1. Precautions for safe handling

Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment.

7.2. Conditions for safe storage, including any incompatibilities

Storage recommended at room temperature Keep away from food, drink and feed. Incompatible materials: None in particular.

Instructions as regards storage premises:

Adequately ventilated premises.

7.3. Specific end use(s) None in particular

Section 8: Exposure controls and personal protection

8.1. Control parameters

No occupational exposure limit available

DNEL Exposure Limit Values

N.A.

PNEC Exposure Limit Values

N.A.

8.2. Exposure controls

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Protection for skin:

Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.

Protection for hands:

Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374) 

Respiratory protection:

Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with medium /high efficiency for solid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Thermal Hazards: None Environmental exposure controls:

None

Appropriate engineering controls:

None 

Section 9: Physical data and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Method  
Appearance and colour LIQUID YELLO -- --
Odour Characteristic -- --
Odour threshold N.A. -- --
pH 5 -- --
Melting point / freezing point -5 degrees C -- --
Initial boiling point and boiling range 100 degrees C -- --
Flash point: > 100 degrees C -- --
Evaporation rate: N.A. -- --
Soild / gas flammability N.A. -- --
Upper / lower flammability N.A. -- --
Vapour pressure N/A/ -- --
Vapour density N.A. -- --
Relative density 1.05 -- --
Solubility in water soluble -- --
Solubility in oil insoluble -- --
Partition coefficient (n-octanol/water) N.A. -- --
Auto-ignition temperature N.A. -- --
Decomposition temperature N.A. -- --
Viscosity N.A. -- --
Explostive properties N.A. -- --
Oxidising properties N.A. -- --

9.2. Other information

Properties Value Method  
Miscibility N.A. -- --
Fat Solubility N.A. -- --
Conductivity N.A. -- --
Substance Groups relevant properties N.A. -- --
       

 

Section 10: Stability & Reactivity

10.1. Reactivity

Stable under normal conditions

10.2. Chemical stability

Stable under normal conditions

10.3. Possibility of hazardous reactions 

None 

10.4. Conditions to avoid

Stable under normal conditions.

10.5. Incompatible materials

None in particular.

10.6. Hazardous decomposition products

None.

Section 11: Toxicological Information

11.1. Information on toxicological effects

Toxicological information of the product:

a) acute toxicity

Not classified
Based on available data, the classification criteria are not met

b) skin corrosion/irritation

Not classified
Based on available data, the classification criteria are not met

c) serious eye damage/irritation

The product is classified: Eye Dam. 1 H318

d) respiratory or skin sensitisation

Not classified
Based on available data, the classification criteria are not met

e) germ cell mutagenicity

Not classified
Based on available data, the classification criteria are not met

f) carcinogenicity

Not classified
Based on available data, the classification criteria are not met

g) reproductive toxicity

Not classified
Based on available data, the classification criteria are not met

h) STOT-single exposure

Not classified
Based on available data, the classification criteria are not met

i) STOT-repeated exposure

Not classified
Based on available data, the classification criteria are not met

j) aspiration hazard

Not classified
Based on available data, the classification criteria are not met

Toxicological information of the main substances found in the product:

Cocamidopropyl betaine - CAS: 147170-44-3

a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat
8100 mg/kg

c) serious eye damage/irritation:
Test: Eye Irritant - Species: Rabbit
Positive

d) respiratory or skin sensitisation:
Test: Skin Sensitization - Species: Guinea pig
Negative

e) germ cell mutagenicity:
Test: Mutagenesis - Species: Rabbit Negative
Coconut fatty acids - CAS: 61788-47-4
Acute oral toxicity LD50 (rat) > 2000 mg/Kg

Section 12: Ecological information

12.1. Toxicity

Adopt good working practices, so that the product is not released into the environment.

The product is classified: Aquatic Chronic 3 - H412

Cocamidopropyl betaine - CAS: 147170-44-3

a) Aquatic acute toxicity:
Endpoint: LC50 - Species: Fish 25 mg/l - Duration h: 25
Endpoint: EC50 - Species: Daphnia 45 mg/kg - Duration h: 45

12.2. Persistence and degradability

None

Biodegradability: Readily biodegradable - Test: N.A. - Duration: N.A. - %: N.A. - Notes:
Regulation (EC) No. 648/2004

12.3. Bioaccumulative potential

N.A.

12.4. Mobility in soil

N.A.

12.5. Results of PBT and vPvB assessment

vPvB Substances: None - PBT Substances: None

12.6. Other adverse effects

None 

 

Section 13: Disposal considerations

13.1. Waste treatment methods

Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force. 

Section 14: Transport information

14.1. UN number

Not classified as dangerous in the meaning of transport regulations.

14.2. UN proper shipping name

N.A.

14.3. Transport hazard class(es)

N.A.

14.4. Packing group

N.A.

14.5. Environmental hazards Marine pollutant:

No

14.6. Special precautions for user

N.A.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

N.A.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Dir. 98/24/EC (Risks related to chemical agents at work)

Dir. 2000/39/EC (Occupational exposure limit values)

Regulation (EC) n. 1907/2006 (REACH)

Regulation (EC) n. 1272/2008 (CLP)

Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013

Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP)

Regulation (EU) n. 618/2012 (ATP 3 CLP)

Regulation (EU) n. 487/2013 (ATP 4 CLP)

Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP)

Regulation (EU) n. 2015/1221 (ATP 7 CLP)

Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: 

Where applicable, refer to the following regulatory provisions :

Directive 2012/18/EU (Seveso III)

Regulation (EC) nr 648/2004 (detergents).

Dir. 2004/42/EC (VOC directive)

Provisions related to directive EU 2012/18 (Seveso III):

Seveso III category according to Annex 1, part 1 None

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for the mixture. Substances for which a Chemical Safety Assessment has been carried out: None

Section 16: Other information

Text of phrases referred to under heading 3:

H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life

Hazard class and hazard category Code Description
Actue Tox. 4 3.1/4 Acute toxicity (oral), Category 4
Skin Irrit. 2 3.2./2 Skin irritation, Category 2
Eye Dam. 1 3.3/1 Serious eye damage, Category 1
Eye Irrit. 2 3.3/2 Eye irritation, Category 2
Aquatic Acute 1 4.1/A1 Acute aquatic hazard category 1
Aquatic Chronic 3 4.1/C3 Chronic (long term) aquatic hazard, category 3

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: 

Classification according to Regulation (EC) Nr. 1272/2008 Classification procedure 
Eye Dam. 1, H318 Calculation method
Aquatic Chronic 3, H412 Calculation method

Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold

This MSDS cancels and replaces any preceding release.

GMO Declaration

We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material

To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.

Animal Testing Declaration

WE DO NOT TEST ANY OF OUR PRODUCTS ON ANIMALS AND NEVER HAVE, WE PREFER TO RELY ON OUR KNOWLEDGE OF ESSENTIAL OILS, INGREDIENTS, PLANTS, FLOWERS AND ESTABLISHED TECHNICAL INFORMATION AND PROFESSIONALS TO ENSURE EFFECTIVE AND SAFE PRODUCTS.

We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.

Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.

We do not conduct any form of animal testing.

We do not commission any form of animal testing from a third party.

We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006

If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions