Phenoxyethanol & Ethylhexylglycerinby Naturallythinking Safety Data Sheet (SDS)

SDS for Phenoxyethanol & Ethylhexylglycerin

Safety Data Sheet (SDS) dated 25/01/2021

Batch Number: FRAMECPSR


Section 1: Identification of Product and Supplier

Product Name: Phenoxyethanol & Ethylhexylglycerin
Product Number: 5060233389360
Brand: Naturallythinking
Supplier: Naturallythinking, Unit 2 Mill Lane Trading Estate, Mill Lane, Croydon, CR0 4AA
Contact Telephone: 020 38563588
Contact Email: support@naturallythinking.eu

Section 2: Hazards IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Serious eye damage, Category 1 H318: Causes serious eye damage.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Danger

Hazard statements : H318 Causes serious eye damage.

Precautionary statements : P280 Wear eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor.

Hazardous components which must be listed on the label: 70445-33-9 3-(2-ethylhexyloxy)propane-1,2-diol

Section 3: Composition and information on Ingredients

Inci: Phenoxyethanol & Ethylhexylglycerin
Cas: 122-99-6/70445-33-9
Einecs: 204-589-7/408-080-2

3.2 Mixtures

Chemical Name CAS-No
EC-No
Index No.
Registration number
Classifcation Concentration (% w/w)
2-phenoxyethanol 122-99-6
204-589-7
603-098-00-9
01-2119488943-21-XXXX
Acute Tox.4:H302 88.5-91.5
3-(2-ethylhexyloxy)propane-1,2-diol) 70445-33-9
48-080-2
603-168-00-9
01-0000015745-65-0001
Eye Dam. 1:H318
Acute Tox 4: H332
Aquatic Chronic 3: H413
8.5-11.15

 

Section 4: First aid measures

4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.

If inhaled : If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with plenty of water.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

If swallowed : Obtain medical attention.

5.1 Extinguishing media Suitable extinguishing media : Water Dry powder Foam Carbon dioxide (CO2) Unsuitable extinguishing media : No information available. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : No information available. 5.3 Advice for firefighters Further information : Standard procedure for chemical fires.Symptoms : Risk of serious damage to eyes.

Risks : No information available.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment : No information available

Section 5: Fire - Fighting measures

5.1 Extinguishing media

Suitable extinguishing media : Water Dry powder Foam Carbon dioxide (CO2)

Unsuitable extinguishing media : No information available.

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting : No information available.

5.3 Advice for firefighters

Further information : Standard procedure for chemical fires.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

6.4 Reference to other sections

see Section 8 + 13

Section 7: Handling and Storage

7.1 Precautions for safe handling

Advice on safe handling : Handle and open container with care.

Advice on protection against fire and explosion : No special protective measures against fire required.

Hygiene measures : Take off all contaminated clothing immediately.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers : Store in original container.

Further information on storage conditions : Keep away from direct sunlight. Limited stability - see label on pack. Keep container tightly closed.

Advice on common storage : Keep away from food and drink.

7.3 Specific end use(s)

Specific use(s) : none

Section 8: Exposure controls and personal protection

Substance name End Use Exposure routes Potential health effects Value
2-phenoxyethanol Workers Inhalation Long-term systemic effects, Long-term local effects 8.07 mg/m3
  Workers Skin contact Long-term systemic effects 34.72 mg/kg
  Consumers Inhalation Lon-term exposure, Short-term exposture, Local effects 2.5 mg/m3
  Consumers Skin contact Long-term local effects 20.83 mg/kg
  Consumers Ingestion Short-term exposure, Long-term exposure, Systemic effects 17.43 mg/kg
3-(2-ethylhexyloxy)propane-1,2-diol Workers Inhalation Acute systemic effects 1.55 mg/m3
  Workers Inhalation Long-term systemic effects 0.875 mg/m3
  Workers Skin contact Long-term systemic effects 1mg/kg
  Consumers Inhalation Long-term systemic effects 0.109 mg/m3
  Consumers Skin contact Long-term systemic effects 0.5 mg/kg

Predicted no Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006

Substance name Environmental Compartment  Value
2-phenoxyethanol  Fresh Water 0,943 mg/l
  Marine Water 0,0943 mg/l
  Fresh water sediment 7,2366 mg/kg
  Marine sediment 0,7237 mg/kg
  Soil 1,26 mg/kg
  Intermittent use/release 3,44 mg/l
  Sewage treatment plant 24,8 mg/l
3-(2-ethylhexyloxy)propane-1,2-diol Fresh water 0,15 mg/l
  Marine water 0,015 mg/l
  Fresh water sediment 0,19 mg/kg
  Marine sediment 0,019 mg/kg
  Soil 0,894 mg/kg
  Sewage treatment plant 5,6 mg/l
     

8.2 Exposure controls

Personal protective equipment

Eye protection : Safety glasses with side-shields conforming to EN166

Hand protection : Impervious glovesSplash protection: disposable nitrile rubber gloves e.g. Dermatril (layer thickness: 0.11 mm) made by KCL or gloves from other manufacturers offering the same protection.Prolonged contact: Butyl rubber gloves e.g. Butoject (>480 Min., layer thickness: 0.70 mm) made by KCL or gloves from other manufacturers offering the same protection.

Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Protective measures : Avoid contact with skin and eyes.

Section 9: Physical data and chemical properties

9.1 Information on basic physical and chemical properties A

ppearance : liquid Colour : nearly colourless

Odour : characteristic

Odour Threshold : not determined

pH : 6 - 8 (20 C)

Concentration: 10 g/l

Freezing point : ca. 5 C

Boiling point/boiling range : > 100 C

Flash point : > 100 C Method: ISO 2719

Evaporation rate : not determined

Flammability (solid, gas) : Not applicable

Upper explosion limit / Upper flammability limit : Not applicable

Lower explosion limit / Lower flammability limit : Not applicable

apour pressure : not determined

Vapour density : not determined

Relative density : ca. 1,087 - 1,092 g/ml (20 C)

Solubility(ies) Water solubility : 10 g/l (20 C)

Partition coefficient: noctanol/water : Not applicable

Auto-ignition temperature : Not applicable

Viscosity Viscosity, dynamic : 28 mPa*s Method: Rheo WIN RS 600

Flow time : < 15 s at 20 C Method: DIN 53211

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

9.2 Other information

Surface tension : 34 mN/m

Refractive index : 1,522 - 1,534 at 20 C

Self-ignition : Not applicable

Section 10: Stability & Reactivity

10.1 Reactivity

Stable under recommended storage conditions.

10.2 Chemical stability

No decomposition if stored normally.

10.3 Possibility of hazardous reactions

Hazardous reactions : None reasonably foreseeable.

10.4 Conditions to avoid

Conditions to avoid : Protect from frost, heat and sunlight.

10.5 Incompatible materials

Materials to avoid : No data available

10.6 Hazardous decomposition products

None reasonably foreseeable.

Section 11: Toxicological Information

11.1 Information on toxicological effects

Acute toxicity

Components:

2-phenoxyethanol:

Acute oral toxicity : LD50 (Rat): 1.850 mg/kg Assessment: Harmful if swallowed.

Acute inhalation toxicity : (Rat): Exposure time: 8 h Remarks: An LC50/ inhalation could not be determined because no mortality of rats was observed at the maximum achievable concentration.

Acute dermal toxicity : LD50: > 2.000 mg/kg Remarks: Based on available data, the classification criteria are not met.

3-(2-ethylhexyloxy)propane-1,2-diol:

Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on available data, the classification criteria are not met.

Acute inhalation toxicity : LC50 (Rat): 3,07 mg/l Method: OECD Test Guideline 403 Assessment: Harmful if inhaled.

Acute dermal toxicity : LD50 (Rat): > 2.000 mg/kg Method: OECD Test Guideline 402 Remarks: Based on available data, the classification criteria are not met.

Skin corrosion/irritation

Components:

2-phenoxyethanol:

Species : Rabbit

Method : OECD Test Guideline 404

Result : No skin irritation

3-(2-ethylhexyloxy)propane-1,2-diol:

Method : OECD Test Guideline 404

Result : slight irritation

Remarks : Based on available data, the classification criteria are not met.

Serious eye damage/eye irritation

Components:

2-phenoxyethanol:

Species : Rabbit Assessment : Causes serious eye irritation.

Method : OECD Test Guideline 405

3-(2-ethylhexyloxy)propane-1,2-diol:

Method : OECD Test Guideline 405

Result : Risk of serious damage to eyes.

Test substance : concentrate

Respiratory or skin sensitisation

Components:

2-phenoxyethanol:

Test Type : Maximisation Test

Species : Guinea pig

Method : OECD Test Guideline 406

Result : Did not cause sensitisation on laboratory animals.

3-(2-ethylhexyloxy)propane-1,2-diol:

Method : OECD Test Guideline 406

Result : Did not cause sensitisation on laboratory animals.

Germ cell mutagenicity

Components:

2-phenoxyethanol:

Germ cell mutagenicity- Assessment : Tests on bacterial or mammalian cell cultures did not show mutagenic effects.

3-(2-ethylhexyloxy)propane-1,2-diol:

Genotoxicity in vitro : Method: OECD Test Guideline 471 Result: Not mutagenic in Ames Test

Genotoxicity in vivo : Method: OECD 474 Remarks: Micronucleus test: not mutagenic

Carcinogenicity

Components:

2-phenoxyethanol:

Carcinogenicity - Assessment : No data available

Reproductive toxicity

Components:

2-phenoxyethanol:

Reproductive toxicity - Assessment :

Animal testing did not show any effects on fertility.

3-(2-ethylhexyloxy)propane-1,2-diol:

Effects on foetal development :

Species: Rat

Application Route: Oral

General Toxicity Maternal: NOAEL: 800 mg/kg body weight Method: OECD Test Guideline 414

STOT - single exposure

Components:

2-phenoxyethanol:

Remarks : Based on available data, the classification criteria are not met.

STOT - repeated exposure

Components:

2-phenoxyethanol:

Remarks : No data available

Repeated dose toxicity

Components:

2-phenoxyethanol:

Species : Rat

NOAEL : 400 mg/kg

Application Route : Oral

Remarks : Based on available data, the classification criteria are not met.

3-(2-ethylhexyloxy)propane-1,2-diol:

Species : Rat

NOAEL : 100 mg/kg

Application Route : Oral

Exposure time : 28-day

Method : OECD Test Guideline 407

Remarks : Based on available data, the classification criteria are not met.

Species : Rat

NOAEL : 50 mg/kg

Application Route : Oral

Exposure time : 90-day

Aspiration toxicity

No data available

Section 12: Ecological information

12.1 Toxicity

Components:

2-phenoxyethanol:

Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): > 100 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates : EC50 : > 500 mg/l Exposure time: 48 h

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 500 mg/l Exposure time: 72 h

Toxicity to fish (Chronic toxicity) : NOEC: 23 mg/l Exposure time: 34 d Species: Pimephales promelas (fathead minnow)

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 9,43 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea)

3-(2-ethylhexyloxy)propane-1,2-diol:

Toxicity to fish : LC50 (Brachidanio rerio): 60,2 mg/l Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna): 78,3 mg/l Exposure time: 48 h Method: OECD Test Guideline 202

Toxicity to algae : IC50 (Desmodesmus subspicatus (green algae)): 48,3 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to microorganisms : EC50 : 560 mg/l Method: OECD 209

Toxicity to fish (Chronic toxicity) : NOEC: 1,5 mg/l Exposure time: 35 d Species: Brachidanio rerio Method: OECD Test Guideline 210

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 20 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Method: OECD Test Guideline 211

12.2 Persistence and degradability

Components: 2-phenoxyethanol:

Biodegradability : Biodegradation: 90 - 100 % Exposure time: 15 d Method: OECD Test Guideline 301A Remarks: According to the results of tests of biodegradability this product is considered as being readily biodegradable.

3-(2-ethylhexyloxy)propane-1,2-diol:

Biodegradability : Result: According to OECD criteria, the product is inherently biodegradable. Method: OECD 302B/ ISO 9888/ EEC 88/302C

12.3 Bioaccumulative potential

Components:

2-phenoxyethanol:

Bioaccumulation : Bioconcentration factor (BCF): 0,35 Remarks: No bioaccumulation is to be expected (log Pow <= 4).

Partition coefficient: noctanol/water : log Pow: 1,16

3-(2-ethylhexyloxy)propane-1,2-diol:

Partition coefficient: noctanol/water : log Pow: 2,53

12.4 Mobility in soil

Product:

Mobility : Remarks: No data available

Components:

2-phenoxyethanol:

Mobility : Remarks: Mobile in soils

12.5 Results of PBT and vPvB assessment

Product:

Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher..

12.6 Other adverse effects

Product:

Adsorbed organic bound halogens (AOX) : Remarks: Product does not contain any organic halogens.

Section 13: Disposal considerations

13.1 Waste treatment methods

Product : Dispose of as hazardous waste in compliance with local and national regulations. The product should not be allowed to enter drains, water courses or the soil.

Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.

Waste key for the unused product(Group) : The waste producer itself must, in consultation with the appropriate authorities and a waste disposal company, obtain a waste code from the EWC (European Waste Catalogue)

Section 14: Transport information

14.1 UN number

Not regulated as a dangerous good

14.2 UN proper shipping name

Not regulated as a dangerous good

14.3 Transport hazard class(es)

Not regulated as a dangerous good

14.4 Packing group

Not regulated as a dangerous good

14.5 Environmental hazards

Not regulated as a dangerous good

14.6 Special precautions for user

Not applicable

For personal protection see section 8.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.

Not applicable

Volatile organic compounds : none, Directive 2010/75/EC on the limitation of emissions of volatile organic compounds

15.2 Chemical safety assessment

Exempt

Section 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed.

H318 : Causes serious eye damage.

H319 : Causes serious eye irritation.

H332 : Harmful if inhaled.

H412 : Harmful to aquatic life with long lasting effects.

Full text of other abbreviations

Acute Tox. : Acute toxicity

Aquatic Chronic : Long-term (chronic) aquatic hazard

Eye Dam. : Serious eye damage

Eye Irrit. : Eye irritation

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative

Further information

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) No. 1272/2008

Eye Dam. 1, H318 : Calculation method

http://ec.europa.eu/health/ph_risk/committees/sccp/docshtml/sccp_out59_en.htm

Notes to animal Testing

No animal testing has been performed by Naturallythinking. Where there is reference to animal testing it is using historical information publicly available or data that has been obtained by suppliers inline with EU Cosmetic Regulations before our self imposted Animal Testing Cut Off date

GMO Declaration

We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material

To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.

Animal Testing Declaration

WE DO NOT TEST ANY OF OUR PRODUCTS ON ANIMALS AND NEVER HAVE, WE PREFER TO RELY ON OUR KNOWLEDGE OF ESSENTIAL OILS, INGREDIENTS, PLANTS, FLOWERS AND ESTABLISHED TECHNICAL INFORMATION AND PROFESSIONALS TO ENSURE EFFECTIVE AND SAFE PRODUCTS.

We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.

Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.

We do not conduct any form of animal testing.

We do not commission any form of animal testing from a third party.

We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006

If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions