Butylene glycol Dicaprylate / Dicaprateby Naturallythinking Safety Data Sheet (SDS)

SDS for Butylene glycol Dicaprylate / Dicaprate

Safety Data Sheet (SDS) dated 29/03/2024

Batch Number: FRAMECPSR


Section 1: Identification of Product and Supplier

Product Name: Butylene glycol Dicaprylate / Dicaprate
Product Number: 5060330638644
Brand: Naturallythinking
Supplier:
UK: Naturallythinking, Unit 2 Mill Lane Trading Estate, Mill Lane, Croydon, CR0 4AA
EU: NTEU Ltd (HE 426545), Nikis 1, Anthoupoli, 2350, Nicosia, Cyprus
Contact Telephone: 020 38563588
Contact Email: support@naturallythinking.eu

Section 2: Hazards IDENTIFICATION

2.1 Classification of the substance or mixture

· Classification according to Regulation (EC) No 1272/2008 The substance is not classified according to the CLP regulation.

2.2 Label elements

· Labelling according to Regulation (EC) No 1272/2008 Void

· Hazard pictograms: Void

· Signal word: Void

· Hazard statements Void

2.3 Other hazards

· Results of PBT and vPvB assessment

· PBT: Not applicable
· vPvB: Not applicable

Section 3: Composition and information on Ingredients

Inci: Butylene glycol Dicaprylate / Dicaprate
Cas: 211107-84-5
Einecs: 424-180-9

3.1 Chemical characterisation: Substances

· CAS No. Description:

reaction mass of: but-1,3-diyl didecanoate, but-1,3-diyldioctanoate, but-1,3-diyl 1-decanoate-3-octanoate, but-1,3-
diyl 1-octanoate-3-decanoate

· Identification number(s):

· ELINCS Number: 424-180-9

Section 4: First aid measures

4.1 Description of first aid measures

· General information:

If symptoms persist or in case of doubt, seek medical advice.
Never give anything by mouth to an unconscious person.

· After inhalation: Inhalation of product is unlikely.
· After skin contact: Wash with water and soap.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:

Rinse mouth with water.
Never give anything by mouth to an unconscious person.

If symptoms persist, consult doctor.

4.2 Most important symptoms and effects, both acute and delayed

No further relevant information available.

4.3 Indication of any immediate medical attention and special treatment needed

Symptomatic treatment

Section 5: Fire - Fighting measures

5.1 Extinguishing media

· Suitable extinguishing agents:

Carbon dioxide (CO₂)
Fire-extinguishing powder
Foam
Use fire fighting measures that suit the environment.

· For safety reasons unsuitable extinguishing agents: Water

5.2 Special hazards arising from the substance or mixture

In case of fire, the following can be released:
Noxious gases/vapours

5.3 Advice for firefighters

· Protective equipment:

Do not inhale combustion vapours.
Wear self-contained respiratory protective device.

· Additional information: Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Product forms slippery surface when combined with water.

Wear protective clothing.

6.2 Environmental precautions:

Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.

6.3 Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Make sure to recycle or dispose of in suitable receptacles.

6.4 Reference to other sections See Section 8 for information on personal protection equipment.

Section 7: Handling and Storage

7.1 Precautions for safe handling No special measures required.

· Information about protection against explosions and fires: Observe the general rules of industrial fire protection.

7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles: Not required
· Information about storage in one common storage facility:

Store away from foodstuffs.
Store away from feed.

· Further information about storage conditions: None
· Storage class: 10 Combustible liquids

· 7.3 Specific end use(s) No further relevant information available

Section 8: Exposure controls and personal protection

Additional information about design of technical systems:

Mechanical ventilation/exhaustion is strongly recommended.
No further data; see section 7.

8.1 Control parameters

· Components with limit values that require monitoring at the workplace: Not required
· Additional information: The lists that were valid during the creation were used as basis.

8.2 Exposure controls

· Personal protective equipment:
· General protective and hygienic measures: The usual precautionary measures should be adhered to when handling chemicals.

· Breathing equipment:

At formation of aerosols and mist:
Short term filter device:
Filter A-P2
Full mask with filter: ABEK-P2
Breathing equipment is only to be used in order to handle the residual risk of short term jobs if all other risk minimizing measures
have been carried out e.g. retention and/or local exhaust.

· Protection of hands:

Protective gloves
The glove material has to be impermeable and resistant to the product/substance/preparation.
Due to missing tests no recommendation to the glove material can be given for the product / preparation / chemical mixture.
Selection of the glove material in consideration of the penetration times, rates of diffusion and the degradation

· Material of gloves:

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.
Nitrile rubber, NBR
Recommended thickness of the material: ≥ 0.35 mm
Butyl rubber, BR
Recommended thickness of the material: ≥ 0.5 mm

· Penetration time of glove material:
≥ 30 min

The exact penetration time has to be found out by the manufacturer of the protective gloves and has to be observed.

· Eye protection: Goggles recommended during refilling

· Body protection: Protective work clothing

Section 9: Physical data and chemical properties

Appearance

Form: Liquid
Colour: Light Yellow
Odour Threshold: Not Applicable
pH: Not Determined

Change in Condition
Melting Point / Melting Range: -25.8c
Boiling Point / Boiling Range: Not determined

Flash Point: 191c

Danger of Explosion: Product does not present an explosion hazard

Vapour Pressure at 20c: < 0.01hPA
Density at 20c: ~0.91 g/cm3
Solubility in / Miscibility with Water at 20c: <0.001g/l

Section 10: Stability & Reactivity

10.1 Reactivity

No further relevant information available

10.2 Chemical stability

· Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications

10.3 Possibility of hazardous reactions

No dangerous reactions known

10.4 Conditions to avoid

Strong heating
Dirt
Chemical contamination
Sunlight, UV or ionizing radiation

10.5 Incompatible materials: No further relevant information available

10.6 Hazardous decomposition products:
No hazardous decomposition products if instructions for storage and handling are followed

Section 11: Toxicological Information

11.1 Information on toxicological effects

· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values that are relevant for classification:

Oral LD50 > 2000 mg/kg (rat) (OECD 401)
Dermal LD50 > 2000 mg/kg (rat) (OECD 402)

· Primary irritant effect:
· Skin corrosion/irritation

Light irritation OECD Method: 404
Not to be classified

· Serious eye damage/irritation No irritating effect species: rabbit (eye) OECD test 405
· Respiratory or skin sensitisation

No sensitisation species: guinea pig OECD 406
No sensitising effect in guinea pig in maximation test

· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity

Oral NOAEL (F1) 1000 mg/kg bw/day (rat) (OECD 416)
NOAEL (F2) 1000 mg/kg bw/day (rat) (OECD 416)
NOAEL (P) 1000 mg/kg bw/day (rat) (OECD 416)
NOAEL (maternal) 1000 mg/kg bw/day (rat) (OECD 414)
NOAEL(canc) 1000 mg/kg bw/day (rat) (OECD 414)

Based on available data, the classification criteria are not met.

· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure

Oral NOAEL 1000 mg/kg/day (rat) (OECD 407)
28 d
1000 mg/kg bw/d (rat) (OECD 408)
28 d
Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

Section 12: Ecological information

12.1 Toxicity
Aquatic toxicity:

No harmful effect on fish, daphnia and algae up to its limit of solubility.
EC50 >1100 mg/l (Bacteriae) (OECD TG 209)
3h
264 mg/l (Plants) (OECD 208)
Avena sativa
LC50/14d >1000 mg/l (Eisenia foetida) (OECD TG 207)

12.2 Persistence and degradability No further relevant information available
· Other information:
The product is readily biodegradable.
Biological degradation: > 60% after 28 days
OECD TG 301 B
· 12.3 Bioaccumulative potential No further relevant information available
· 12.4 Mobility in soil
Low potential for adsorption to soil
High mobility in soil

· Adsorption coefficient Koc: 3.7
· Additional ecological information:
· General notes: Generally not hazardous for water
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable
· vPvB: Not applicable
· 12.6 Other adverse effects No further relevant information available

Section 13: Disposal considerations

13.1 Waste treatment methods

· Recommendation: Disposal according to instructions of local authorities
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

Section 14: Transport information

14.1 UN-Number
· ADR, ADN, IMDG, IATA Void

14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void

14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void

14.4 Packing group
· ADR, IMDG, IATA Void

14.5 Environmental hazards:
· Marine pollutant: No

14.6 Special precautions for user 
Not applicable

14.7 Transport in bulk according to Annex II of Marpol and
the IBC Code Not applicable

· Transport/Additional information: Not dangerous according to the above regulations
· UN "Model Regulation": Void

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Directive 2012/18/EU
Named dangerous substances - ANNEX I Substance is not listed.

National regulations

Water hazard class:

Generally not hazardous for water
Ident number.: 2956

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

Section 16: Other information

References:

European Chemicals Agency

European Chemicals Bureau

European Regulations and Directives

Published chemical directories

Suppliers’ safety data sheets

UK Health and Safety Executive

US Environmental Protection Agency

Risk Phrases

R38: Irritating to skin.

R41: Risk of serious damage to eyes.

Safety Phrases

S25: Avoid contact with eyes.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S39: Wear eye/face protection.

Hazard statement(s)

H315: Causes skin irritation.

H318: Causes serious eye damage.

Precautionary statement(s)

P262: Do not get in eyes, on skin, or on clothing.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

GMO Declaration

We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material

To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.

Animal Testing Declaration

UK: As set out under the conditions in Schedule 34 - Amendment of Regulation (EC) No 1223/2009 and related amendments of The Product Safety and Metrology etc. (Amendment etc.) (EU Exit) Regulations 2019 neither the cosmetic nor its component product has been tested on animal purposes

EU:As set out in under the conditions in 1223/2009. Art. 15 Nar. Parliament and the Council of the EU 952/2013 neither the cosmetic nor its component product has been tested on animal purposes

WE DO NOT TEST ANY OF OUR PRODUCTS ON ANIMALS AND NEVER HAVE, WE PREFER TO RELY ON OUR KNOWLEDGE OF ESSENTIAL OILS, INGREDIENTS, PLANTS, FLOWERS AND ESTABLISHED TECHNICAL INFORMATION AND PROFESSIONALS TO ENSURE EFFECTIVE AND SAFE PRODUCTS.

We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.

Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.

We do not conduct any form of animal testing.

We do not commission any form of animal testing from a third party.

We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006

If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions