Climbazoleby Naturallythinking Safety Data Sheet (SDS)

SDS for Climbazole

Safety Data Sheet (SDS) dated 24/05/2024

Batch Number: FRAMECPSR

Section 1: Identification of Product and Supplier

Product Name: Climbazole
Product Number: 5060330639238
Brand: Naturallythinking
UK: Naturallythinking, Unit 2 Mill Lane Trading Estate, Mill Lane, Croydon, CR0 4AA
EU: NTEU Ltd (HE 426545), Nikis 1, Anthoupoli, 2350, Nicosia, Cyprus
Contact Telephone: 020 38563588
Contact Email:

Section 2: Hazards IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4, Oral - H302
Acute aquatic toxicity, Category 1 - H400
Chronic aquatic toxicity, Category 1 - H410

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms


Signal word:


Hazard statements:

H302 Harmful if swallowed.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements:

P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.

Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P391 Collect spillage.

Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.


2.3 Other hazards

No data available

Section 3: Composition and information on Ingredients

Inci: Climbazole
Cas: 38083-17-9
Einecs: 253-775-4

3.1 Substances

Chemical Characterisation Molecular Weight Total Formula CAS No. EINECS-No. Reach Registration No.
Climbazole 292,76 g/mol C15-H17-Cl-N2-O2 38083-17-9 253-775-4 01-2119615553-43-0000

3.2 Mixtures

Hazardous components: Not applicable

Section 4: First aid measures

4.1 Description of first aid measures

General advice:

Move out of dangerous area.
Never give anything by mouth to an unconscious person.


Move to fresh air.

Skin contact:

If symptoms persist, call a physician.

Eye contact:

Immediately flush eye(s) with plenty of water.


Clean mouth with water and drink afterwards plenty of water.
Prevent vomiting if possible.
If a person vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person.
If accidentally swallowed obtain immediate medical attention.

4.2 Most important symptoms and effects, both acute and delayed

No data available

4.3 Indication of any immediate medical attention and special treatment needed

No data available

Section 5: Fire - Fighting measures

5.1 Extinguishing media

Suitable extinguishing media:

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which shall not be used for safety reasons:

High volume water jet

5.2 Special hazards arising from the substance or mixture:

Specific hazards during firefighting:

Do not use a solid water stream as it may scatter and spread fire.
Do not allow run-off from fire fighting to enter drains or water courses.

5.3 Advice for firefighters

Special protective equipment for firefighters:

In the event of fire, wear self-contained breathing apparatus.

Further information:

In the event of fire and/or explosion do not breathe fumes.
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions:

Ensure adequate ventilation.
Use personal protective equipment.

6.2 Environmental precautions

Environmental precautions:

Should not be released into the environment.
Avoid subsoil penetration.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up:

Pick up and transfer to properly labelled containers.
Use mechanical handling equipment.
Dam up.

Additional advice:

Local authorities should be advised if significant spillages cannot be contained.

6.4 Reference to other sections

For personal protection see section 8.

Section 7: Handling and Storage

7.1 Precautions for safe handling

Advice on safe handling:

Dispose of rinse water in accordance with local and national regulations.
For personal protection see section 8.

Advice on protection against fire and explosion:

When using do not smoke.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers:

Store in original container.
Keep container tightly closed in a dry and well-ventilated place.
To maintain product quality, do not store in heat or direct sunlight.

Advice on common storage:

No special restrictions on storage with other products.

Other data:

No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Cosmetic ingredient

Section 8: Exposure controls and personal protection

8.1 Control parameters




End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 0,3 mg/m3

End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 4,28 mg/kg bw/day



Compartment: Fresh water
Value: 0,00052 mg/l

Compartment: Fresh water sediment
Value: 0,29 mg/kg dry weight (d.w.)

Compartment: Marine water
Value: 0,000052 mg/l

Compartment: Marine sediment
Value: 0,029 mg/kg dry weight (d.w.)

Compartment: Sewage treatment plant
Value: 100 mg/l

Compartment: Soil
Value: 0,64 mg/kg dry weight (d.w.)

8.2 Exposure controls

Engineering measures


Personal protective equipment

Respiratory protection: Half mask with a particle filter P2 (EN 143)

Hand protection: Wear chemicals-resistant gloves, e.g. safety gloves of chloroprene Level 2 or of butyl rubber Level 6.

Eye protection: Safety glasses

Skin and body protection: Lightweight protective clothing

Hygiene measures: Do not breathe dust or spray mist. Wash hands before breaks and immediately after handling the product.

Protective measures: Do not breathe dust.When using do not eat, drink or smoke.




Section 9: Physical data and chemical properties

Form: White powder

Section 10: Stability & Reactivity

10.1 Reactivity

Reacts with Strong oxidising agents and acids

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

None known

10.4 Conditions to avoid

High temperatures

10.5 Incompatible materials

Strong oxidising agents. Strong acids

10.6 Hazardous Decomposition Product(s)

None known

Section 11: Toxicological Information

No toxicological data available

Section 12: Ecological information

12.1 Toxicity

(Fish) (96hrs): NOEC> 0.4mg/l (> limit of solubility)(Stearyl alcohol)

(Daphnia magna) (48hrs): EC50 > 0.01 mg/L (> limit of solubility)(Cetyl alcohol)

(Algae) (72hrs): EC50 > 0.01 mg/l (> limit of solubility)(Cetyl alcohol)

12.2 Persistence and degradability

Readily biodegradable.

12.3 Bioaccumulative potential (96 hrs)

The product has moderate potential for bioaccumulation.

12.4 Mobility in soil

This product is predicted to degrade in soil.

12.5 Results of PBT and vPvB assessment

Not classified as PBT or vPvB.

12.6 Other adverse effects

None recorded

Section 13: Disposal considerations

13.1 Waste treatment methods

Material to be disposed of as hazardous waste. Normal disposal is via incineration operated by an accredited disposal contractor. Consult an accredited waste disposal contractor or the local authority for advice.

13.2 Additional Information


Section 14: Transport information

14.1 Land transport (ADR/RID)

UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.

14.2 Sea transport (IMDG)

UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.

14.3 Air transport (ICAO/IATA)

UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU regulations: EC Standards 82/242 and 82/243/EEC (Detergents) : This product is > 90% biodegradable in water.

15.1.2 National regulations: None assigned

15.2 Chemical Safety Assessment: No Chemical Safety Assessment (CSA) has been carried out

Section 16: Other information


European Chemicals Agency

European Chemicals Bureau

European Regulations and Directives

Published chemical directories

Suppliers’ safety data sheets

UK Health and Safety Executive

US Environmental Protection Agency

Risk Phrases

R38: Irritating to skin.

R41: Risk of serious damage to eyes.

Safety Phrases

S25: Avoid contact with eyes.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S39: Wear eye/face protection.

Hazard statement(s)

H315: Causes skin irritation.

H318: Causes serious eye damage.

Precautionary statement(s)

P262: Do not get in eyes, on skin, or on clothing.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

GMO Declaration

We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material

To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.

Animal Testing Declaration

UK: As set out under the conditions in Schedule 34 - Amendment of Regulation (EC) No 1223/2009 and related amendments of The Product Safety and Metrology etc. (Amendment etc.) (EU Exit) Regulations 2019 neither the cosmetic nor its component product has been tested on animal purposes

EU:As set out in under the conditions in 1223/2009. Art. 15 Nar. Parliament and the Council of the EU 952/2013 neither the cosmetic nor its component product has been tested on animal purposes


We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.

Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.

We do not conduct any form of animal testing.

We do not commission any form of animal testing from a third party.

We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006

If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions